|
The
links below are to to the 400 MHz H NMR spectra for each of the given
compounds either as Adobe .pdf files or as the raw FID data that may
then be worked up using a program such as MestRe-C.
In order to have all the required data for each sample (fid, text, log,
procpar), the files are zipped and may be extracted using a utility
such as WinZip.
The spectra were collected on a Varian Gemini 2000 system and should be
worked up using the VarianVXR-Unity option in MestRe-C, which does not
require the VHELPER converter.
The
Adobe Acrobat files contain H, integrated 1H
and expansion plots as well as line lists for coupling constant
analysis and ChemDraw structures of each compound. The Acrobat Reader
is free from Adobe.
There
will also be made available Chime models of each compound, which may be
useful in at least a rough analysis of the dihedral angles between
protons. The models were built using PC Spartan and may be viewed using
the Chime plugin and
each model may be saved by using the "right click save as" option on
your mouse.
|
|
Sample
|
Spectra |
FID
data
|
Chime
|
A
|
1,2,3,4,6-penta-O-acetyl-alpha-D-
glucopyranose
|
1H
A |
FID
A |
|
B
|
1,2,3,4,6-penta-O-acetyl-beta-D-
glucopyranose
|
1H
B |
FID
B |
|
C
|
1-bromo-1-deoxy-2,3,4,6-tetra-O-
acetyl-alpha-D-glucopyranose
|
1H
C |
FID
C |
C
|
D
|
1-azido-1-deoxy-2,3,4,6-tetra-O-
acetyl-beta-D-glucopyranose
|
1H
D |
FID
D |
D
|
E
|
3,5-di-O-acetyl-1,2-O-isopropylidene-
alpha-D-xylofuranose
|
1H
E |
FID
E |
E
|
F
|
methyl 2,3,4,6-tetra-O-acetyl-alpha-
D-glucopyranoside
|
1H
F |
FID
F |
F
|
G
|
methyl 2,3,4,6-tetra-O-acetyl-alpha-
D-mannopyranoside
|
1H
G |
FID
G |
G
|
H
|
1,2,3,4-tetra-O-acetyl-beta-D-glucuronic
acid methyl
ester
|
1H
H |
FID
H |
H
|
I
|
1-bromo-1-deoxy-2,3,4-tri-O-acetyl-alpha-
D-glucuronic
acid methyl ester
|
1H
I |
FID
I |
I
|
J
|
1-azido-1-deoxy-2,3,4-tri-O-acetyl-beta-D-
glucuronic
acid methyl ester
|
1H
J |
FID
J |
J
|
|
|